Basic Concepts for Electrical Circuit (PART-2)- ( Energy of an Electron, Valence Electrons, Free Electrons, conductor, insulator, semiconductor)

In previous PART-1 we have seen that nature of electricity, unit of charge, and about electron.

here we will see that what is energy of electron, valance electron, free electron, and about the insulator, conductor and semi-conductor.

1). Energy of an Electron-

An electron moving around the nucleus possesses two types of energies viz. kinetic energy due to its motion and potential energy due to the charge on the nucleus. The total energy of the electron is the sum of these two energies. The energy of an electron increases as its distance from the nucleus increases. Thus, an electron in the second orbit possesses more energy than the electron in the first orbit ; electron in the third orbit has higher energy than in the second orbit. It is clear that electrons in the last orbit possess very high energy as compared to the electrons in the inner orbits. These last orbit electrons play an important role in determining the physical, chemical and electrical properties of a material.

2). Valence Electrons-

The electrons in the outermost orbit of an atom are known as valence electrons.

The outermost orbit can have a maximum of 8 electrons i.e. the maximum number of valence electrons can be 8. The valence electrons determine the physical and chemical properties of a material. These electrons determine whether or not the material is chemically active; metal or non-metal or, a gas or solid. These electrons also determine the electrical properties of a material. On the basis of electrical conductivity, materials are generally classified into conductors, insulators and semi-conductors. As a rough rule, one can determine the electrical behavior of a material from the number of valence electrons as under : 

(A) When the number of valence electrons of an atom is less than 4 (i.e. half of the maximum eight electrons), the material is usually a metal and a conductor. Examples are sodium, magnesium and aluminum which have 1, 2 and 3 valence electrons respectively. 

(B) When the number of valence electrons of an atom is more than 4, the material is usually a non-metal and an insulator. Examples are nitrogen, Sulphur and neon which have 5, 6 and 8 valence electrons respectively. 

(C) When the number of valence electrons of an atom is 4 (i.e. exactly one-half of the maximum 8 electrons), the material has both metal and non-metal properties and is usually a semi-conductor. Examples are carbon, silicon and germanium.

3). Free Electrons-

 The electrons in the inner orbits (i.e., orbits close to the nucleus) are tightly bound to the nucleus. As we move away from the nucleus, this binding goes on decreasing so that electrons in the last orbit (called valence electrons) are quite loosely bound to the nucleus. In certain substances, especially metals (e.g. copper, aluminum etc.), the valence electrons are so weakly attached to their nuclei that they can be easily removed or detached. Such electrons are called free electrons. Those valence electrons which are very loosely attached to the nucleus of an atom are called free electrons.

The free electrons move at random from one atom to another in the material. Infect, they are so loosely attached that they do not know the atom to which they belong. It may be noted here that all valence electrons in a metal are not free electrons. It has been found that one atom of a metal can provide at the most one free electron.

we can also define the materials according to free electron as stated below-

(a) A substance which has a large number of free electrons at room temperature is called a conductor of electricity e.g. all metals. If a voltage source (e.g. a cell) is applied across the wire of a conductor material, free electrons readily flow through the wire, thus constituting electric current. The best conductors are silver, copper and gold in that order. Since copper is the least expensive out of these materials, it is widely used in electrical and electronic industries. 

(b) A substance which has very few free electrons is called an insulator of electricity. If a voltage source is applied across the wire of insulator material, practically no current flows through the wire. Most substances including plastics, ceramics, rubber, paper and most liquids and gases fall in this category. Of course, there are many practical uses for insulators in the electrical and electronic industries including wire coatings, safety enclosures and power-line insulators. 

(c) There is a third class of substances, called semi-conductors. As their name implies, they are neither conductors nor insulators. These substances have crystalline structure and contain very few free electrons at room temperature. Therefore, at room temperature, a semiconductor practically behaves as an insulator. However, if suitable controlled impurity is imparted to a semi-conductor, it is possible to provide controlled conductivity. Most common semi-conductors are silicon, germanium, carbon etc. However, silicon is the principal material and is widely used in the manufacture of electronic devices (e.g. crystal diodes, transistors etc.) and integrated circuits.

NOTE- Energy band theory is also used to define the insulator, conductor and semi-conductor.